Valium /ˈvæl.i.əm/ noun2 •The drug diazepam.These are the minor tranquilizers such as Diazepam (Valium), Chlordiazepoxide (Librium), Oxazepam (Serax), and related benzodiazepines, and Meprobamate, which are used to treat anxiety neurosis. — 1979 •A Valium pill. formsValiums