Barcelona UK /ˌbɑːsəˈləʊnə/US /ˌbɑɹsəˈloʊnə/ noun3 •The capital city of Catalonia, Spain.Sarah Harvey, an NHS worker from Brighton, was also told by Vodafone that she had to pay a £5,800 bill run up after she was hit on the head by a cyclist, again in Barcelona this summer. — 2014 •A province of Catalonia, Spain. •The capital city of the state of Anzoátegui, Venezuela.