barleycorn /ˈbɑː(ɹ)liˌkɔː(ɹ)n/ noun3 •A grain of barley.The Town Mouse came, and they sat down to a dinner of barleycorns and roots, the latter of which had a distinctly earthy flavour. — 1912 •A small groove between two moldings. •(no longer used) The length of such a grain; a unit of length of approximately one third (or sometimes one quarter) of an inch or eight millimetres, still used as a basis for shoe sizes.This trip to Italy has actually enlarged the diameter of my head thirteen barleycorns! — 1879 formsbarleycorns